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oleandomycin biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
TDP-3-dimethylamino-4,6-dideoxy-alpha-D-glucopyranose + L-oleandrosyl-oleandolide <=> oleandomycin + dTDP + H+ 2.4.1

8,8a-deoxyoleandolide + O2 <=> Oleandolide + H2O 1.14.13

S-adenosyl-L-methionine + L-olivosyl-oleandolide <=> S-adenosyl-L-homocysteine + L-oleandrosyl-oleandolide + H+ 2.1.1.239 L-olivosyl-oleandolide 3-O-methyltransferase

Oleandolide + dTDP-L-olivose <=> L-olivosyl-oleandolide + dTDP + H+ 2.4.1

acetyl-CoA + (S)-methylmalonyl-CoA + NADPH + H+ <=> 8,8a-deoxyoleandolide + CO2 + CoA + H2O + NADP+ 2.3.1

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